The aim of this work was to assess the use of antibiotic byproduct biomass as a biosorbent for methylene blue removal from wastewater. Adsorption of pyridine onto activated montmorillonite. Moisture sorption isotherms and heat of sorption of algerian bay. Adsorption, chemisorption, and catalysis article pdf available in chemical papers 6812 september 2014 with 18,016 reads how we measure reads. The adsorption of organic matter was followed by spectrophotometry at 470 nm, and the adsorption data were a good fit with freundlich isotherm for puri. The adsorption was achieved on activated algerian clay in batch mode. The moisture sorption isotherms of algerian bay leaves laurus nobilis were. Sorption study of a basic dye gentian violet from aqueous. Article pdf available in journal of surface engineered materials. Algerian journal of environmental science and technology. The objective of this study is the variation of natural and modified clays and their use in industrial waste treatment. Desorption studies desorption studies can elucidate the nature of adsorption and recycling of the adsorbent and the dye.
The results indicate that the langmuir model provides the best correlation qmax 35. In this paper, we report a theoretical study of the physisorption of molecular hydrogen, h2, on a major component of the interstellar dust known as polycyclic aromatic hydrocarbons pahs. Activated montmorillonite was applied for the sorption of pyridine as a healthtoxic substance. The effect of adsorption of plasticization in the journal. Adsorption phase equilibrium is an important theory to analyze the adsorption separation technology and is the basis of describing an adsorption capacity of adsorbed molecules in adsorbents and adsorptive selectivity. Preparation and characterization of modified peekwc. The adsorption isotherms at different temperatures have been used for the determination of thermodynamic parameters i.
In this study, adsorption of picric acid was studied from aqueous solutions by using a weakly basic adsorbent amberlite ira67 at three different temperatures 298 k, 308 k, and 318 k. Fouriertransform infrared spectroscopy ftir, zeta potential analysis, thermogravimetric analysis tga, n2 physisorption analysis and xray diffraction xrd method were used to investigate the structure and composition of montmorillonite. Canadian journal of chemistry canadian science publishing. The adsorption isotherms were modeled with langmuir, freundlich, temkin, hasley and harkins models and their isotherm constants were calculated. The system does not contain any movable part, and the author has obtained a cop between 0. Removal properties, mechanisms, and performance of methyl. Information about the openaccess article corrosion inhibition of carbon steel a 283 c using the acetylsalicylic acid in doaj. Removal of malathion from polluted water by adsorption onto chemically. The international journal of applied ceramic technology publishes cuttingedge applied research and development work focused on commercialization of engineered ceramics, products and processes. Glp about gas chromatography, dissolution, atomic adsorption spectroscopy, titration, ph meter and. The average weight of adsorbent loaded in the column was around 100 mg. It was found that the adsorption of the metal ions followed pseudosecondorder kinetic model. Article pdf available in journal of applied sciences research 2. Removal of malathion from polluted water by adsorption onto.
Adsorption isotherms adsorption is a separation process in which some materials, adsorbate is concentrated from a bulk vapor or liquid phase on to the surface of a porous solid adsorbent. Adsorption study of the removal of paraphenylenediamine ppd using activated carbon based cameroonian canarium ovatum shells impregnated with zncl2 and h3po4 written by pierre gerard tchieta, caroline lincold nintedem magapgie, jacques bomiko mbouombouo published on 20190902 download full article with reference data and citations. The pictorial representation is intended to attract the attention of the readership. A dye adsorption capacity of activated carbon for the ro16 is 147. Therefore, the biosorption of the cationic dye methylene blue by spent biomass of pleurotus mutilus. An assessment of the surface properties of milled attapulgite using. The effect of various experimental parameters was investigated using a batch adsorption technique.
Adsorption of cationic methyl green mg on nontreated ab and purified ap natural sejnane clay type was studied in an equilibrium batch process. Effects of algerians clays properties on the adsorption of. Results of thermodynamic studies for bb66, ab29 and dr2 dyes adsorption at different initial concentrations. The freundlich model fits the data with a monolayer adsorption capacity of 166. The specific surface was measured by the bet technique using isothermal n. The batch sorption system was used to study the effect of. Results of activation energy for bb66, ab29 and dr2. Mayor 6 made an adsorption refrigerator working with the pair silica gelwater. Adsorption of congo red from aqueous solution using ctab. A graphical abstract ga is now optional for all submissions. Both of the adsorption isoterm, the r2 value of langmuir isotherm.
Adsorption article about adsorption by the free dictionary. Related content insitu deposition of hematite fe2o3 microcubes on cotton cellulose via. Pdf adsorption of congo red from aqueous solution using. Blue methylene retrieval using silicasalicylic acid modified. Currently, the plant is cultivated in many countries such as turkey, algeria, france, greece. This journal is a member of the committee on publication ethics cope. Isoterm adsorpsi langmuir metilen biru dengan paduan silikaasam salisilat from publication. Journal of membrane science and research 4206 2018 204211 2. Thermodynamic treatment of adsorption data showed an exothermic nature of adsorption. Valorization of the spent biomass of pleurotus mutilus. Two different density functional theory approaches were. Characterization of phosphate adsorption on sediments. Cystophloroketals ae 15, five new phloroglucinolmeroditerpenoid hybrids, have been isolated together with their putative biosynthetic precursor, the monocyclic meroditerpenoid 6, from the mediterranean brown alga cystoseira tamariscifolia. Urban wastewater treatment by adsorption of organic.
Liehui zhang, in developments in petroleum science, 2019. Langmuir, freundlich, tempkin, dubininraduskevich isotherm models were applied for the analysis of isotherm data. Adsorptive removal of phenol from aqueous solution on a modified palm shellbased carbon. Characterization and physicochemical treatment of elkerma algeria landfill leachates by batch adsorption on untreated. Atomic adsorption spectroscopy, titration, ph meter and conductivity meter. The production of antibiotics in algeria generates large amounts of residual biomass that should be considered a valuable biosorbent rather than waste. Effects of contact time, initial dye concentration, mass adsorbent, ph, and temperature on the mg removal were checked. The ga illustrates a process or clarifies a specific aspect of the work, ideally an innovation or novel component. Synthesis of mesoporous titania with surfactant and its. The journal adsorption provides authoritative information on adsorption and. For that, in the same system used for the adsorption, desorption experiments were carried out with nitric acid at.
Pdf adsorption of congo red from aqueous solution using ctab. The adsorption column was made from pyrex glass tubing 5mm inside diameter and 100mm in length. Infrared data of of bentonite, djebal debbagh clay and kaolin. The use of linear and nonlinear methods for adsorption.
Thermodynamics of adsorption showed that the values obtained for our sample confirm well the interactions with phenol and 4ahb are physical in nature. Adsorptiondesorption isotherm of sample using n2 at 77 k 350 400 450 500 550 600 0 20. Adsorption is one of the most effective processes for removing. Adsorption isotherms, kinetics, thermodynamics and. Pure and doped hydroxyapatite ha nanocrystalline powders ca10. Design and realization of a solar adsorption refrigeration. The objective of this study was to evaluate the performance of combined processes. For research on gassolid adsorption phase equilibrium, categorization. To illustrate the adsorption process for quantitative description, fig.
While freundlich constants k f and n can be obtained from the intercept and the slope of ln q e vs ln c eq plots, with n indicating the favourableness n1 of the adsorption process and k f the adsorption capacity of the adsorbent. This work reported the application of kaoliniterich heterogeneous clay for the removal of a cationic dye. Adsorbate molecule a in the bulk fluid phase diffuses through the solvent or mixture to the external surfaces of the solid matrices 1, next diffuses through the internal pores of the solid matrix, reaching the active center. Cetyltrimethylammonium bromidemodified kaolin ctabkaolin or kc was prepared and tested as an adsorbent for an anionic dye congo red cr removal from aqueous solution in comparison with natural kaolin k. In this manner, the adsorption isotherms and adsorption kinetics of cr on k and kc were. Batch adsorption studies revealed that the potential of aleppo pine. Usually the amount adsorbed is only a fraction of a monolayer.
The band at 521 and 461cm1 was from the sioal where al is an octahedral cation. The procedure for the deprotonation reaction of the calcined substrate substrate activation is also described in the same literature were the substrate is chemically treated with a naoh 0. Conference series paper open access synthesis of nanocrystalline fe2o3 by using thermal oxidation of fe films to cite this article. They represent the first examples of meroditerpenoids linked to a phloroglucinol through a 2,7dioxabicyclo3. The effect of adsorption of plasticization in the journal bearings vehicle diesel engines nadezhda marina. Cooperative adsorption on solid surfaces sciencedirect. Abstract the article discussed and solved the problem of. A solar adsorption refrigerator was built and tested in 2000 by hildbrand 3 in switzerland using the pair silica gelwater. For this purpose, we carried out several elimination tests of the effluents by adsorption by using two natural clays from different deposits, namely bentonite located in maghnia and djabel debbagh of ain berbar and bentonite coupled with cellulose. Adsorption, kinetics, isotherm, mesoporous materials, phenol, p. Langmuir constant related to the rate of adsorption k l lmg are obtained from c eq e vs c e plots. Adsorption of congo red from aqueous solution using ctabkaolin from bechar algeria article pdf available in journal of surface engineered materials and advanced technology 0406.
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